Oxygen- and Sulfur-Capped Organotin Clusters
The synthesis and structural features of the oxygen-capped cluster, [( n -BuSn(OH)O 2 P (OBu t ) 2 ) 3 O] [O 2 P(OBu t ) 2 ] ( l ), are compared to that of the analogous formulations containing framework sulfur atoms in place of oxygens, [( n -BuSn(S) (OH)OP(OBu t ) 2 ) 3 S] [O 2 P(OBu t ) 2 ]·2H 2...
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| Veröffentlicht in: | Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1989-01, Vol.41 (1-2), p.69-74 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The synthesis and structural features of the oxygen-capped cluster, [(
n
-BuSn(OH)O
2
P (OBu
t
)
2
)
3
O] [O
2
P(OBu
t
)
2
] (
l
), are compared to that of the analogous formulations containing framework sulfur atoms in place of oxygens, [(
n
-BuSn(S) (OH)OP(OBu
t
)
2
)
3
S] [O
2
P(OBu
t
)
2
]·2H
2
S·H
2
O (
2
) and [(
n
-BuSn)
3
(S)(O)(O
2
CPh)
5
] (
3
). Solution NMR,
119
Sn and
31
P, indicate that the solid state structures determined by X-ray analysis are retained in solution. |
|---|---|
| ISSN: | 1042-6507 1563-5325 |
| DOI: | 10.1080/10426508908039694 |