Oscillatory recombination and isomerization of reactor irradiated trans-/Co(en)2Cl2/NO3

The oscillatory reconstitution of the parent entity during isothermal treatment of the reactor irradiated trans-/Co(en) 2 Cl 2 /NO 3 is analogous to oscillatory isomerization proceeding independently but probably following the same driving mechanism of defects formed during irradiation. Thermodynami...

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Veröffentlicht in:	Radiation effects and defects in solids 1990-02, Vol.112 (4), p.211-220
Hauptverfasser:	Dimotakis, P. N., Papaefthymiou, H.
Format:	Artikel
Sprache:	eng
Schlagworte:	isomerization NO Oscillatory recombination reactor irradiation trans-/Co(en)
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Beschreibung
Zusammenfassung:	The oscillatory reconstitution of the parent entity during isothermal treatment of the reactor irradiated trans-/Co(en) 2 Cl 2 /NO 3 is analogous to oscillatory isomerization proceeding independently but probably following the same driving mechanism of defects formed during irradiation. Thermodynamics of irreversible processes concepts and the Volterra-Lotka mechanism are used to support theoretically the experimental results.
ISSN:	1042-0150 1029-4953
DOI:	10.1080/10420159008213047