THE SYNTHESIS OF 1,3,2-DIOXAPHOSPHOLENES. EVIDENCE FOR AN ARYLOXYPHOSPHINIDENE INTERMEDIATE

THE SYNTHESIS OF 1,3,2-DIOXAPHOSPHOLENES. EVIDENCE FOR AN ARYLOXYPHOSPHINIDENE INTERMEDIATE

The reaction of 2,6-di-t-butyl-4-methylphenylphosphorodichloridite with α-diketones in the presence of magnesium metal affords modest yields of 1,3,2-dioxaphospholenes. This may be the first evidence for the existence of the monocoordinate aryloxyphosphinidene intermediate, ROP.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Phosphorus and sulfur and the related elements 1987-12, Vol.34 (3-4), p.149-154
1. Verfasser: Chasar, Dwight W.
Format: Artikel
Sprache:eng
Schlagworte:
1,3,2-dioxaphospholenes
aryloxyphosphinidine
arylphosphorodichloridite
Chemistry
Exact sciences and technology
heterocycle
magnesium
Organic chemistry
Organometalloidal and organometallic compounds
P derivatives
Preparations and properties
α-diketone
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The reaction of 2,6-di-t-butyl-4-methylphenylphosphorodichloridite with α-diketones in the presence of magnesium metal affords modest yields of 1,3,2-dioxaphospholenes. This may be the first evidence for the existence of the monocoordinate aryloxyphosphinidene intermediate, ROP.
ISSN:0308-664X
DOI:10.1080/03086648708074319