Formation and chemical behaviour of silylated phosphanes
Our investigations to be presented here have their origin in a number of former results: The formation of [(Me 3 Si) 2 P] 2 SiMe 2 [1] and its rearrangement to P 4 (SiMe 2 ) 6 (a molecule with adamantane structure) and P(SiMe 3 ) 3 , the formation of P 7 (SiMe 3 ) 3 and of some cyclic phosphanes by...
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| Veröffentlicht in: | Phosphorus and sulfur and the related elements 1983-12, Vol.18 (1-3), p.65-68 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Our investigations to be presented here have their origin in a number of former results: The formation of [(Me
3
Si)
2
P]
2
SiMe
2
[1] and its rearrangement to P
4
(SiMe
2
)
6
(a molecule with adamantane structure) and P(SiMe
3
)
3
, the formation of P
7
(SiMe
3
)
3
and of some cyclic phosphanes by the thermally induced rearrangement of [(Me
3
Si)
2
)P]
2
SiMe
2
[3], and the formation of P
7
(SiMe
3
)
3
by reacting P
4
with Na/K-alloy and Me
3
SiCl. After finding LiP(SiMe
3
)
2
to be such a versatile reagent we turned to elucidate synthesis and chemical behaviour of LiP[P(SiMe
3
)
2
]
2
. |
|---|---|
| ISSN: | 0308-664X |
| DOI: | 10.1080/03086648308075968 |