THE REACTION OF DIMETHYL SULFOXIDE AND SYM-DICHLORO-BIS(2,4,6-TRICHLOROPHENYL) UREA

THE REACTION OF DIMETHYL SULFOXIDE AND SYM-DICHLORO-BIS(2,4,6-TRICHLOROPHENYL) UREA

Sym-dichloro-bis(2,4,6-trichlorophenyl) urea reacts explosively with dimethyl sulfoxide to yield phosgene, formaldehyde, methane, sulfur dioxide, ethylene chloride, methylene dichloride, chlorinated disulfides, and insoluble bis(2,4,6-trichlorophenyl) urea. The products, other than bis(2,4,6-trichlo...

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Veröffentlicht in:Phosphorus and sulfur and the related elements 1976-12, Vol.2 (1-3), p.177-180
Hauptverfasser: Owens, C., Hall, R., Mitchell, T., Chasen, D., Gelfand, L., Pytlewski, L. L.
Format: Artikel
Sprache:eng
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Zusammenfassung:Sym-dichloro-bis(2,4,6-trichlorophenyl) urea reacts explosively with dimethyl sulfoxide to yield phosgene, formaldehyde, methane, sulfur dioxide, ethylene chloride, methylene dichloride, chlorinated disulfides, and insoluble bis(2,4,6-trichlorophenyl) urea. The products, other than bis(2,4,6-trichlorophenyl) urea, are separated and characterized by means of gas chromatography and mass spectrometry. A homolytic mechanism is proposed for the reaction.
ISSN:0308-664X
DOI:10.1080/03086647608078947