Dielectric investigation of proton glass behaviour in a solid solution of deuterated betaine phosphate0.4 betaine phosphite0.6
Measurements of the dielectric permittivity are reported for a deuterated solid solution of antiferroelectric betaine phosphate 0.4 ferroelectric betaine phosphite 0.6 at frequencies 20 Hz < v < 1 MHz. Freezing phenomena in DBP 0.4 DBPI 0.6 have revealed a transition into a dipolar glass state...
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Veröffentlicht in: | Phase transitions 1998-04, Vol.64 (4), p.229-238 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | Measurements of the dielectric permittivity are reported for a deuterated solid solution of antiferroelectric betaine phosphate
0.4
ferroelectric betaine phosphite
0.6
at frequencies 20 Hz < v < 1 MHz. Freezing phenomena in DBP
0.4
DBPI
0.6
have revealed a transition into a dipolar glass state. The activation energy was found to be E
b
= 469 K (0.041 eV). The Kutnjak model showed typical glass behaviour with an estimated glass temperature of 37 K. |
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ISSN: | 0141-1594 1029-0338 |
DOI: | 10.1080/01411599808208001 |