Synthesis of Tetrakis(isopropylisocyanide)bis(1,2-bis{diphenyl-arsino}ethane)cobalt(II) Perchlorate. Monodentate Coordination by a Normally Chelating Bidentate Ligand
The Co(II) complex, [Co(CNCHMe 2 ) 4 (Ph 2 AsCH 2 CH 2 AsPh 2 ) 2 ] (CIO 4 ) 2 , was synthesized by the reaction of [Co 2 (CNCHMe 2 ) 10 ] (ClO 4 ) 4 ˙ 5H 2 O with excess Ph 2 AsCH 2 CH 2 AsPh 2 . Characterization data in the solid state are consistent with six-coordinate, tetragonal coordination in...
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| Veröffentlicht in: | Synthesis and reactivity in inorganic and metal-organic chemistry 1994-06, Vol.24 (5), p.855-865 |
|---|---|
| 1. Verfasser: | |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The Co(II) complex, [Co(CNCHMe
2
)
4
(Ph
2
AsCH
2
CH
2
AsPh
2
)
2
] (CIO
4
)
2
, was synthesized by the reaction of [Co
2
(CNCHMe
2
)
10
] (ClO
4
)
4
˙ 5H
2
O with excess Ph
2
AsCH
2
CH
2
AsPh
2
. Characterization data in the solid state are consistent with six-coordinate, tetragonal coordination in which the Ph
2
AsCH
2
CH
2
AsPh
2
ligands are monodentate. This complex has limited stability in solution. |
|---|---|
| ISSN: | 0094-5714 1532-2440 |
| DOI: | 10.1080/00945719408001306 |