Organoruthenium Selenium Complexes. Synthesis of Ru2(CO)2(Cp)2Se3 and Its Reaction with Acid Chlorides
Reaction of [Ru(CO) 2 Cp] 2 with elemental selenium in benzene produced Ru 2 (CO) 2 (Cp) 2 Se 3 . This organoruthenium-selenium compound was reacted with acid chlorides, RCOCI and Se-bonded derivatives of the formula [Cp(CO) 2 RuSeCOR] (R = C 6 H 5 , 3-NO 2 C 6 H 4 , 4-NO 2 C 6 H 4 , C 6 H 4 COCI an...
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| Veröffentlicht in: | Synthesis and reactivity in inorganic and metal-organic chemistry 1994-06, Vol.24 (5), p.715-722 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Reaction of [Ru(CO)
2
Cp]
2
with elemental selenium in benzene produced Ru
2
(CO)
2
(Cp)
2
Se
3
. This organoruthenium-selenium compound was reacted with acid chlorides, RCOCI and Se-bonded derivatives of the formula [Cp(CO)
2
RuSeCOR] (R = C
6
H
5
, 3-NO
2
C
6
H
4
, 4-NO
2
C
6
H
4
, C
6
H
4
COCI and C
6
H
4
COSeRu(CO)
2
Cp), were produced |
|---|---|
| ISSN: | 0094-5714 1532-2440 |
| DOI: | 10.1080/00945719408001296 |