Synthesis of an Intermediate for(±)-Platphyllide Through Thionyl Chloride-Pyridine Mediated Rearrangement

Synthesis of an Intermediate for(±)-Platphyllide Through Thionyl Chloride-Pyridine Mediated Rearrangement

The cyclohexadienyl alcohol (3) on treatment with thionyl chloride and pyridine provided the tetrahydronaphthalene (4) whose transformation to the carbomethoxy tetralone (7), a key intermediate for platphyllide (8), has been accomplished in four steps.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Synthetic communications 1999-09, Vol.29 (17), p.2995-3001
Hauptverfasser: Banerjee, Ajoy K., Azócar, Jose A., Vera, William
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The cyclohexadienyl alcohol (3) on treatment with thionyl chloride and pyridine provided the tetrahydronaphthalene (4) whose transformation to the carbomethoxy tetralone (7), a key intermediate for platphyllide (8), has been accomplished in four steps.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919908086474