Nuclear Monobromination of Alkyl Phenyl Ethers with NaClO2, NaBr, Mn(acac)3, and Moist Silica Gel in Aprotic Solvent
Nuclear monobromination of aromatic ethers can be achieved with a NaClO 2 /NaBr/Mn(acac) 3 catalyst/silica gel system in dichloromethane in regioselective and high-yielding manner under mild conditions.
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| Veröffentlicht in: | Synthetic communications 1998-04, Vol.28 (8), p.1463-1470 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Nuclear monobromination of aromatic ethers can be achieved with a NaClO
2
/NaBr/Mn(acac)
3
catalyst/silica gel system in dichloromethane in regioselective and high-yielding manner under mild conditions. |
|---|---|
| ISSN: | 0039-7911 1532-2432 |
| DOI: | 10.1080/00397919808006845 |