Practical and Efficient 1α-Hydroxylation of 4,4-Dimethyl-2-Ene Derivatives in Terpenic Series

Practical and Efficient 1α-Hydroxylation of 4,4-Dimethyl-2-Ene Derivatives in Terpenic Series

The third part of a triptycal synthesis providing 1α-hydroxy compounds, through microbial hydroxylation in position-3 of terpenoid substrates, followed by dehydration to 4,4-dimethyl-2-ene compounds and subsequent allylic hydroxylation by SeO 2 /pyridine N-oxide, is described.

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Veröffentlicht in:Synthetic communications 1997-01, Vol.27 (1), p.45-60
Hauptverfasser: Aranda, Gérard, Bertranne-Delahaye, Mireille, Azerad, Robert, Maurs, Michèle, Cortés, Manuel, Ramirez, Hector, Vernal, Gonzalo, Prangé, Thierry
Format: Artikel
Sprache:eng
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Zusammenfassung:The third part of a triptycal synthesis providing 1α-hydroxy compounds, through microbial hydroxylation in position-3 of terpenoid substrates, followed by dehydration to 4,4-dimethyl-2-ene compounds and subsequent allylic hydroxylation by SeO 2 /pyridine N-oxide, is described.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919708004804