A Novel Synthesis of DL-proto-, and DL-vibo-Quercitol via 1, 4-Cyclohexadiene

A Novel Synthesis of DL-proto-, and DL-vibo-Quercitol via 1, 4-Cyclohexadiene

Photooxygenation of 1, 4-cyclohexadiene 3 followed by reduction with LiAlH 4 or thiourea gave (25/1)-cyclohex-3-ene-triol 7a. trans-Hydroxylation of triol 7a with three different methods afforded both of proto-quercitol la and vibo-quercitol 2a.

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Veröffentlicht in:Synthetic communications 1997-07, Vol.27 (13), p.2223-2234
Hauptverfasser: Salamci, Emine, Seçen, Hasan, Sütbeyaz, Yasar, Balci, Metin
Format: Artikel
Sprache:eng
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Zusammenfassung:Photooxygenation of 1, 4-cyclohexadiene 3 followed by reduction with LiAlH 4 or thiourea gave (25/1)-cyclohex-3-ene-triol 7a. trans-Hydroxylation of triol 7a with three different methods afforded both of proto-quercitol la and vibo-quercitol 2a.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919708003375