Phenylselenium Trichloride, Preparation and Use as a Vinylic Chlorination Reagent
Phenylselenium trichloride (1) is prepared from benzeneseleninic acid (2) and thionyl chloride and used to effect vinylic chlorination, viz. the conversion of 3-chloro-2-chloromethyl-1-propene (4) into 2-chloromethyl-1,3-dichloro-propene (3).
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| Veröffentlicht in: | Synthetic communications 1996-01, Vol.26 (18), p.3345-3350 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Phenylselenium trichloride (1) is prepared from benzeneseleninic acid (2) and thionyl chloride and used to effect vinylic chlorination, viz. the conversion of 3-chloro-2-chloromethyl-1-propene (4) into 2-chloromethyl-1,3-dichloro-propene (3). |
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| ISSN: | 0039-7911 1532-2432 |
| DOI: | 10.1080/00397919608003737 |