A Novel and Convenient Synthesis of E,E-bis(Styryl) sulfones and E,E-1,4-Diaryl-1,3-butadienes

A Novel and Convenient Synthesis of E,E-bis(Styryl) sulfones and E,E-1,4-Diaryl-1,3-butadienes

The condensation of 2-phenylethanesulfonylacetic acid (4) with araldehydes (5) in presence of a base gave E-styryl-2-phenylethyl sulfones (6) which on dehydrogenation with DDQ (7) yielded E,E-bis-(styrl)sulfones (8). The 8 on treatment with dichlorotris(triphenyl-phosphine)ruthenium(II) catalyst res...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Synthetic communications 1991-08, Vol.21 (15-16), p.1589-1596
Hauptverfasser: Ramana Reddy, M. V., Manjubhashini, A. B., Reddy, S., Ramana Reddy, P. V., Reddy, D. Baskar
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The condensation of 2-phenylethanesulfonylacetic acid (4) with araldehydes (5) in presence of a base gave E-styryl-2-phenylethyl sulfones (6) which on dehydrogenation with DDQ (7) yielded E,E-bis-(styrl)sulfones (8). The 8 on treatment with dichlorotris(triphenyl-phosphine)ruthenium(II) catalyst resulted 1,4-diaryl-1,3-butadienes (9). The configurations of 6, 8 and 9 have been determined based on IR and 1 H NMR spectral data.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919108021058