The Synthesis via Organoiron Complexes of Pedicellanin Methyl Ether and Cuparene

The Synthesis via Organoiron Complexes of Pedicellanin Methyl Ether and Cuparene

a synthetic route to Pedicellanin methyl ether as well as to Cuparene via iron tricarbonyl-cyclohexadienyl cations is reported. The unusual aromatization reaction of the iron tricarbonyl- cyclohexadienyl mojety by iron trichloride is evidencied.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Synthetic communications 1988-11, Vol.18 (16-17), p.2037-2050
Hauptverfasser: Bovicelli, P., Mincione, E.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:a synthetic route to Pedicellanin methyl ether as well as to Cuparene via iron tricarbonyl-cyclohexadienyl cations is reported. The unusual aromatization reaction of the iron tricarbonyl- cyclohexadienyl mojety by iron trichloride is evidencied.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397918808068272