Photorearrangement of Aryl Esters in Micellar Medium
Effect of a micelle (SDS) on the photorearrangement of aryl esters have been investigated. Thus, phenyl, p- and m-cresyl, and 2-naphthyl benzoates yielded the corresponding o-hydroxybenzophenones as a major product in high yield. Phenyl cinnamate gave 2-hydroxychalcone. 2,4,6-Tri-butylphenylbenzoate...
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| Veröffentlicht in: | Synthetic communications 1985-10, Vol.15 (12), p.1113-1121 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Effect of a micelle (SDS) on the photorearrangement of aryl esters have been investigated. Thus, phenyl, p- and m-cresyl, and 2-naphthyl benzoates yielded the corresponding o-hydroxybenzophenones as a major product in high yield. Phenyl cinnamate gave 2-hydroxychalcone. 2,4,6-Tri-butylphenylbenzoate, however, underwent decarboxylation yielding 2,4,6-tri-t-butyl biphenyl in quantitative yield. |
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| ISSN: | 0039-7911 1532-2432 |
| DOI: | 10.1080/00397918508076851 |