An Efficient Synthesis of α-Bromoacetals via a Combined Chemical and Electrochemical Bromination
α-Bromoacetals ( 1 ) are valuable precursors in synthesis of α,β-unsaturated carbonyl compounds ( 2 ), 1-alkoxybutadienes 2 ( 3 ), ketene acetals 3 ( 4 ), 2-methoxyallyl bromides 4 ( 5 ) and other compounds. Because of our interest in the chemistry 5,6 of 3 and 4 we attempted to improve known proced...
Gespeichert in:
| Veröffentlicht in: | Synthetic communications 1980-01, Vol.10 (11), p.821-826 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | α-Bromoacetals (
1
) are valuable precursors in synthesis of α,β-unsaturated carbonyl compounds (
2
), 1-alkoxybutadienes
2
(
3
), ketene acetals
3
(
4
), 2-methoxyallyl bromides
4
(
5
) and other compounds. Because of our interest in the chemistry
5,6
of
3
and
4
we attempted to improve known procedures for the preparation of
1
with the aim to get a short and efficient synthesis of these compounds. |
|---|---|
| ISSN: | 0039-7911 1532-2432 |
| DOI: | 10.1080/00397918008062763 |