An Improved Conversion of Cyclohexanones into 1-Methyl-2-Formylcyclohexenes
The 1,2-disubstituted cyclohexene synthon shown in structure is found in several natural products (e.g. cyclolavandulal, ) 1 as well as in numerous useful synthetic intermediates (e.g. →→ tachysterols) 2 . Our interest in novel applications of electrocyclic reactions to natural products synthesis re...
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| Veröffentlicht in: | Synthetic communications 1974-01, Vol.4 (5), p.297-301 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The 1,2-disubstituted cyclohexene synthon shown in structure
is found in several natural products (e.g. cyclolavandulal,
)
1
as well as in numerous useful synthetic intermediates (e.g.
→→ tachysterols)
2
. Our interest in novel applications of electrocyclic reactions to natural products synthesis required a general synthesis for a variety of structures of type
. |
|---|---|
| ISSN: | 0039-7911 1532-2432 |
| DOI: | 10.1080/00397917408064084 |