A New Path for the Reductive Cleavage of Te-Te Bond by the System of Cp2TiCl2/i-BuMgBr and ITS Utility in Synthesis of Unsymmetrical Tellurides
The cleavage reduction of ditellurides by Cp 2 TiCl 2 /i-BuMgBr lead to nucleophilic tellurides [Cp 2 TiTeAr]. This species reacts with aliphatic bromides to give unsymmetrical tellurides in good yield.
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| Veröffentlicht in: | Synthetic communications 2000-04, Vol.30 (8), p.1365-1369 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The cleavage reduction of ditellurides by Cp
2
TiCl
2
/i-BuMgBr lead to nucleophilic tellurides [Cp
2
TiTeAr]. This species reacts with aliphatic bromides to give unsymmetrical tellurides in good yield. |
|---|---|
| ISSN: | 0039-7911 1532-2432 |
| DOI: | 10.1080/00397910008087163 |