Generation of Acyl Nitroso Compounds by the Oxidation of N-Acyl Hydroxylamines with the Dessmartin Periodinane

Generation of Acyl Nitroso Compounds by the Oxidation of N-Acyl Hydroxylamines with the Dessmartin Periodinane

The oxidation of hydroxamic acids, N-hydroxyureas and N-hydroxycarbamates with the Dess-Martin periodinane generates the corresponding acyl nitroso compounds that react with conjugated dienes to produce the corresponding cycloadducts.

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Veröffentlicht in:Synthetic communications 2000-03, Vol.30 (5), p.947-953
Hauptverfasser: Jenkins, Neil E., Ware, Roy W., Atkinson, Robert N., King, S. Bruce
Format: Artikel
Sprache:eng
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Zusammenfassung:The oxidation of hydroxamic acids, N-hydroxyureas and N-hydroxycarbamates with the Dess-Martin periodinane generates the corresponding acyl nitroso compounds that react with conjugated dienes to produce the corresponding cycloadducts.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397910008087108