Highly Chemoselective Thiocarbonyl Oxidation upon Reaction of 4-Methyl-3-phenyl-2-thiazolidinethione with Singlet Oxygen

Highly Chemoselective Thiocarbonyl Oxidation upon Reaction of 4-Methyl-3-phenyl-2-thiazolidinethione with Singlet Oxygen

4-Methyl-3-phenyl-2-thiazolidinethione was reacted with both photochemically and chemically generated singlet oxygen. Despite reaction conditions which were selected to favor oxidation of the sulfide group, both reactions afforded a single product arising solely from thiocarbonyl oxidation.

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Veröffentlicht in:Spectroscopy letters 1996-09, Vol.29 (6), p.1013-1019
Hauptverfasser: İaçli, Siddik, Astley, Stephen T., Timur, Celil, Altmok, Altan
Format: Artikel
Sprache:eng
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Zusammenfassung:4-Methyl-3-phenyl-2-thiazolidinethione was reacted with both photochemically and chemically generated singlet oxygen. Despite reaction conditions which were selected to favor oxidation of the sulfide group, both reactions afforded a single product arising solely from thiocarbonyl oxidation.
ISSN:0038-7010
1532-2289
DOI:10.1080/00387019608007268