Synthesis and Spectroscopic Studies of Metal (II) Tetracyanonickelate Complexes with 1,3-Thiazolidine-2-thione

Two new Hofmann-type complexes, M (1,3-thiazolidine-2-thione) 2 Ni(CN) 4 (where M = Ni and Cd), were synthesized and characterized by elemental analysis, magnetic susceptibility data, IR and Raman Spectroscopy. Their structure consist of planar infinite polymeric layers of {M-NI(CN) 4 }∞. 1,3-thiazo...

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Veröffentlicht in:	Spectroscopy letters 1995-07, Vol.28 (5), p.773-782
Hauptverfasser:	Karacan, Nurcan, Tufan, Yüksel
Format:	Artikel
Sprache:	eng
Schlagworte:	1,3-thiazolidine-2-thione Hofmann-type complexes IR and Raman spectra
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Two new Hofmann-type complexes, M (1,3-thiazolidine-2-thione) 2 Ni(CN) 4 (where M = Ni and Cd), were synthesized and characterized by elemental analysis, magnetic susceptibility data, IR and Raman Spectroscopy. Their structure consist of planar infinite polymeric layers of {M-NI(CN) 4 }∞. 1,3-thiazolidine-2-thione coordinated to M atom above and below this layers is monodentate and S-bonded in these complexes.
ISSN:	0038-7010 1532-2289
DOI:	10.1080/00387019508009918