Analytical solutions for spin 7/2 line intensities in solid state NMR

Developments in computer algebra have prompted us to reconsider earlier, intractable problems. Here the density matrix of spin 7/2 subject to the first order quadrupolar interaction and excited by a RF pulse is calculated ignoring rapidly oscillating terms. The results are studied for a variety of c...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Molecular physics 1995-04, Vol.84 (5), p.835-844
Hauptverfasser: Ageev, S.Z., Sanctuary, B.C.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Developments in computer algebra have prompted us to reconsider earlier, intractable problems. Here the density matrix of spin 7/2 subject to the first order quadrupolar interaction and excited by a RF pulse is calculated ignoring rapidly oscillating terms. The results are studied for a variety of conditions which scale as the ratio of the quadrupolar coupling constant to the RF pulse amplitude. The line intensities of the central and satellite transition are also investigated.
ISSN:0026-8976
1362-3028
DOI:10.1080/00268979500100591