Analytical solutions for spin 7/2 line intensities in solid state NMR
Developments in computer algebra have prompted us to reconsider earlier, intractable problems. Here the density matrix of spin 7/2 subject to the first order quadrupolar interaction and excited by a RF pulse is calculated ignoring rapidly oscillating terms. The results are studied for a variety of c...
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Veröffentlicht in: | Molecular physics 1995-04, Vol.84 (5), p.835-844 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Developments in computer algebra have prompted us to reconsider earlier, intractable problems. Here the density matrix of spin 7/2 subject to the first order quadrupolar interaction and excited by a RF pulse is calculated ignoring rapidly oscillating terms. The results are studied for a variety of conditions which scale as the ratio of the quadrupolar coupling constant to the RF pulse amplitude. The line intensities of the central and satellite transition are also investigated. |
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ISSN: | 0026-8976 1362-3028 |
DOI: | 10.1080/00268979500100591 |