Hyperfine structure investigations of the excited AO+ state of TlI

Hyperfine splittings in several bands of the A-X system of TlI were measured using laser excitation spectroscopy on a highly collimated molecular beam. The quadrupole coupling constant in the A state and its dependence on the vibrational quantum number ν′ was derived. The results are discussed in a...

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Veröffentlicht in:Molecular physics 1991-07, Vol.73 (4), p.813-818
Hauptverfasser: gen. Schröer, H. Bovensmann, Knöckel, H., Tiemann, E.
Format: Artikel
Sprache:eng
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Zusammenfassung:Hyperfine splittings in several bands of the A-X system of TlI were measured using laser excitation spectroscopy on a highly collimated molecular beam. The quadrupole coupling constant in the A state and its dependence on the vibrational quantum number ν′ was derived. The results are discussed in a simple model with the assumption of an avoided crossing.
ISSN:0026-8976
1362-3028
DOI:10.1080/00268979100101571