14N NQR in substituted aziridines
The 14 N NQR spectra are studied in ten substituted aziridines. The electron distribution in three-membered rings is discussed using the NQR data. The variation of the nitrogen orbital electron populations with substituents, as well as comparison of the 14 N NQR spectra in aziridines and amides havi...
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| Veröffentlicht in: | Molecular physics 1976-10, Vol.32 (4), p.979-988 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The
14
N NQR spectra are studied in ten substituted aziridines. The electron distribution in three-membered rings is discussed using the NQR data. The variation of the nitrogen orbital electron populations with substituents, as well as comparison of the
14
N NQR spectra in aziridines and amides having the same substituents, agrees with the three-centre-bonding scheme (except chloroaziridine). |
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| ISSN: | 0026-8976 1362-3028 |
| DOI: | 10.1080/00268977600102391 |