Nuclear resonance spectra of electrolyte solutions

Nuclear resonance spectra of electrolyte solutions

Bromine 79, bromine 81 and sodium 23 resonances are reported for solutions of bromides in aqueous and non-aqueous solvents. The results indicate that quadrupole coupling at the nuclei of Br - and Na + in solutions of sodium and of calcium bromide arises from ion-solvent interactions, and not ion-ion...

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Veröffentlicht in:Molecular Physics (England) 1963-04, Vol.6 (3), p.289-300
Hauptverfasser: Richards, R.E., Yorke, B.A.
Format: Artikel
Sprache:eng
Schlagworte:
BROMINE 79
BROMINE 81
CALCIUM BROMIDES
CESIUM BROMIDES
CHEMISTRY
ELECTROLYTES
IONS
NUCLEAR MAGNETIC RESONANCE
NUCLEAR MODELS
REACTION KINETICS
SODIUM 23
SODIUM BROMIDES
SOLUTIONS
SPECTRA
WATER
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Beschreibung
Zusammenfassung:Bromine 79, bromine 81 and sodium 23 resonances are reported for solutions of bromides in aqueous and non-aqueous solvents. The results indicate that quadrupole coupling at the nuclei of Br - and Na + in solutions of sodium and of calcium bromide arises from ion-solvent interactions, and not ion-ion interactions. In the case of caesium bromide solutions, ion-ion interactions are important.
ISSN:0026-8976
1362-3028
DOI:10.1080/00268976300100331