On the structural study of Pb2ScTaO6-type crystals by analytical electron microscopy and Raman scattering

High resolution electron microscopy, convergent beam electron diffraction and Raman scattering reveal that Pb 2 ScTaO 6 crystals belong to the Fm3m space group. They can be more or less ordered at the atomic scale in the Sc:Ta arrangement resulting in the existence of microdomains. Disordering is ac...

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Veröffentlicht in:Ferroelectrics 1990-07, Vol.107 (1), p.241-246
Hauptverfasser: Boulesteix, C., Caranoni, C., Kang, C. Z., Sapozhnikova, L. S., Siny, I. G., Smirnova, T. A.
Format: Artikel
Sprache:eng
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Zusammenfassung:High resolution electron microscopy, convergent beam electron diffraction and Raman scattering reveal that Pb 2 ScTaO 6 crystals belong to the Fm3m space group. They can be more or less ordered at the atomic scale in the Sc:Ta arrangement resulting in the existence of microdomains. Disordering is accompanied by a broadening of phonon modes up to the line splitting.
ISSN:0015-0193
1563-5112
DOI:10.1080/00150199008221545