Dielectric properties of K1-x Lix TaO3 at frequencies 10-2 - 103 Hz

Dielectric spectrum ε*(ν) = ε(ν) + iε''(ν) and hysteresis loops P(E) have been studied as functions of frequency ν and temperature T in single crystals of K1-x Lix TaO3 with x = 0.10 and 0.15. The position of ε''(T) maximum is shifted to low temperatures as the frequency decrease...

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Veröffentlicht in:Ferroelectrics 1986-07, Vol.69 (1), p.275-282
Hauptverfasser: Smolensky, G. A., Nadolinskaya, E. G., Yushin, N. K., Shilnikov, A. V.
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Sprache:eng
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Zusammenfassung:Dielectric spectrum ε*(ν) = ε(ν) + iε''(ν) and hysteresis loops P(E) have been studied as functions of frequency ν and temperature T in single crystals of K1-x Lix TaO3 with x = 0.10 and 0.15. The position of ε''(T) maximum is shifted to low temperatures as the frequency decreases. In the low-temperature phase (T < T0) the saturated hysteresis loops P(E) are observed. The coercive field and spontaneous polarization increase with cooling of the sample. There are two relaxation regions of ε*(ν) in Cole-Cole plots. The first one is for 10-103 Hz and the second one is for 10-2-103 Hz.On the basis of these experimental data we conclude that the low-temperature phase in K1-x LixTaO3 has a ferroelectric nature rather than polar glass one.
ISSN:0015-0193
1563-5112
DOI:10.1080/00150198608008200