Electron Impact and Chemical Ionization Mass Spectral Analysis of a Volatile Uranyl Derivative

Quadrupole mass spectral analysis of the volatile uranium ligand complex bis (1,1,1,5,5,5-hexafluoro-2,4 pentanedionato) dioxouranium-di-n-butyl sulfoxide is described utilizing electron impact (EI) and methane chemical ionization (CI) ion sources. All major ions are tentatively identified and the p...

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Veröffentlicht in:	Anal. Lett.; (United States) 1981-01, Vol.14 (7), p.553-565
Hauptverfasser:	Reutter, Dennis J., Hardy, Dennis R.
Format:	Artikel
Sprache:	eng
Schlagworte:	400104 - Spectral Procedures- (-1987) ACTINIDE COMPLEXES ACTINIDE ISOTOPES ACTINIDE NUCLEI ALPHA DECAY RADIOISOTOPES COMPLEXES EVEN-EVEN NUCLEI EVEN-ODD NUCLEI HEAVY NUCLEI INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOMERIC TRANSITION ISOTOPES ISOTOPE RATIO ISOTOPES MASS SPECTRA MASS SPECTROSCOPY mass spectrum MINUTES LIVING RADIOISOTOPES NUCLEI RADIOISOTOPES SPECTRA SPECTROSCOPY uranium URANIUM 235 URANIUM 238 URANIUM COMPLEXES uranium complexes diketones uranium isotope determination URANIUM ISOTOPES uranyl URANYL COMPLEXES YEARS LIVING RADIOISOTOPES
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Zusammenfassung:	Quadrupole mass spectral analysis of the volatile uranium ligand complex bis (1,1,1,5,5,5-hexafluoro-2,4 pentanedionato) dioxouranium-di-n-butyl sulfoxide is described utilizing electron impact (EI) and methane chemical ionization (CI) ion sources. All major ions are tentatively identified and the potential usefulness of this complex for determining uranium isotope 235 U /238 U abundance is demonstrated.
ISSN:	0003-2719 1532-236X
DOI:	10.1080/00032718108081427