Electrical and reliability characteristics of an ultrathin TaOxNy gate dielectric prepared by ND3 annealing of Ta2O5

This letter describes a unique process for the preparation of high quality tantalum oxynitride (TaO/sub x/N/sub y/) via the ND/sub 3/ annealing of Ta/sub 2/O/sub 5/, for use in gate dielectric applications. Compared with tantalum oxide (Ta/sub 2/O/sub 5/), a significant improvement in the dielectric...

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Veröffentlicht in:IEEE electron device letters 2000-12, Vol.21 (12), p.563-565
Hauptverfasser: Jung, Hyungsuk, Im, Kiju, Yang, Dooyoung, Hwang, Hyunsang
Format: Artikel
Sprache:eng
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Zusammenfassung:This letter describes a unique process for the preparation of high quality tantalum oxynitride (TaO/sub x/N/sub y/) via the ND/sub 3/ annealing of Ta/sub 2/O/sub 5/, for use in gate dielectric applications. Compared with tantalum oxide (Ta/sub 2/O/sub 5/), a significant improvement in the dielectric constant was obtained by the ammonia treatment followed by light reoxidation in a wet ambient. We were able to confirm nitrogen incorporation in the tantalum oxynitride (TaO/sub x/N/sub y/) by Auger electron spectroscopy. Compared with NH/sub 3/ nitridation, tantalum oxynitride prepared by nitridation in ND/sub 3/ shows less charge trapping and larger charge-to-breakdown characteristics.
ISSN:0741-3106
1558-0563
DOI:10.1109/55.887466