Effect of Reentrant Twin Corners on Directional Solidification of Polycrystalline Silicon

The solidification microstructure and crystal orientation have been investigated for solar cell grade high purity polycrystalline silicon through a unidirectional solidification technique. In the solidification velocity range of 1.25-2.5times10 -6 m/s, the grain size enlarges as solidification progr...

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description The solidification microstructure and crystal orientation have been investigated for solar cell grade high purity polycrystalline silicon through a unidirectional solidification technique. In the solidification velocity range of 1.25-2.5times10 -6 m/s, the grain size enlarges as solidification progresses. Furthermore, large columnar grains contain many twin boundaries. However, in above the critical velocity around 40times10 -6 m/s, equiaxed structure appears. A model of two-dimensional nucleation on the reentrant corner was established, and the critical nucleus could be estimated to be 70 % to 80 % of the radius of the general two-dimensional nucleus. The reduction of the critical radius and undercooling on the reentrant corner could influence on the priority growth direction and the enlargement of the grain size
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source IEEE Electronic Library (IEL) Conference Proceedings
subjects Crystal microstructure
Furnaces
Grain boundaries
Grain size
Morphology
Optical scattering
Photovoltaic cells
Photovoltaic systems
Silicon
Temperature
title Effect of Reentrant Twin Corners on Directional Solidification of Polycrystalline Silicon
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