Studies in Energy Transfer. III. The Effect of Added Gases on the Decomposition of Cyclobutane

Studies in Energy Transfer. III. The Effect of Added Gases on the Decomposition of Cyclobutane

The effect of the addition of hydrogen, helium, neon, argon, nitrogen, methane, water, benzotrifluoride, toluene and mesitylene on the first-order rate constant for the decomposition of cyclobutane at low pressures has been measured. The results are compared with those obtained for the same gases un...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences Mathematical and physical sciences, 1953-07, Vol.218 (1134), p.416-421
Hauptverfasser: Pritchard, H. O., Sowden, R. G., Trotman-Dickenson, A. F.
Format: Artikel
Sprache:eng
Schlagworte:
Activation energy
Chemical bonding
Energy transfer
Gases
Hydrogen
Isomerization
Low pressure
Methane
Molecules
Water pressure
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The effect of the addition of hydrogen, helium, neon, argon, nitrogen, methane, water, benzotrifluoride, toluene and mesitylene on the first-order rate constant for the decomposition of cyclobutane at low pressures has been measured. The results are compared with those obtained for the same gases under similar conditions for the isomerization of cyclopropane.
ISSN:1364-5021
0080-4630
1471-2946
2053-9169
DOI:10.1098/rspa.1953.0114