Laser‐Empowered Random Metasurfaces for White Light Printed Image Multiplexing

Printed image multiplexing based on the design of metasurfaces has attracted much interest in the past decade. Optical switching between different images displayed directly on the metasurface is performed by altering the parameters of the incident light such as polarization, wavelength, or incidence angle. When using white light, only two‐image multiplexing is implemented with polarization switching. Such metasurfaces are made of nanostructures perfectly controlled individually, which provide high‐resolution pixels but small images and involve long fabrication processes. Here, it is demonstrated that laser processing of nanocomposites offers a versatile low‐cost, high‐speed method with large area processing capabilities for controlling the statistical properties of random metasurfaces, allowing up to three‐image multiplexing under white light illumination. By independently controlling absorption and interference effects, colors in reflection and transmission can be varied independently yielding two‐image multiplexing under white light. Using anisotropy of plasmonic nanoparticles, a third image can be multiplexed and revealed through polarization changes. The design strategy, the fundamental properties, and the versatility of implementation of these laser‐empowered random metasurfaces are discussed. The technique, applied on flexible substrate, can find applications in information encryption or functional switchable optical devices, and offers many advantages for visual security and anticounterfeiting. Printed image multiplexing with visualization of three different color images under white light is enabled by switching the angle of observation along with the white light polarization. Its implementation is performed by laser marking, thanks to the control of the statistical properties of plasmonic nanoparticles and the optical thickness of their host matrix.