Interfacial Assembly of Surfactant-Decorated Nanoparticles: On the Rheological Description of a Colloidal 2D Glass

We address the rheology of assemblies of surfactant-decorated silica nanoparticles irreversibly adsorbed at the gas/liquid interface. Positively charged surfactant molecules (such as CTAB) bind to silica nanoparticle surfaces, and the resulting particle–surfactant complexes adsorb at gas/liquid interfaces. The surfactant molecules control the wettability of such decorated nanoparticles and their adsorption. The interparticle forces can be tuned by changing the surfactant concentration C s. Increasing C s, in addition to a decrease of the particles wettability, leads to an increase of the area fraction of particles at the interface. Oscillatory shear measurements (strain- and frequency-sweep) have been performed. Here, we explore the effect of the surfactant concentration C s. At high enough C s, the interface is highly packed, and an overall solidlike response is observed, with 2D glass properties.