Copper‐Mediated Decarboxylative Amidination: Synthesis of O‐Methyl‐N‐Alkylnitroisoureas

Copper‐catalyzed decarboxylation of peroxides in the presence of O‐methyl‐N‐nitroisourea provides an access to O‐methyl‐N‐alkylnitroisoureas, an underdeveloped class of nitrogenated compounds, which can be regarded as isocyanate surrogates and find useful as AB‐type monomers, for polyurethane synthe...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Advanced synthesis & catalysis 2024-05, Vol.366 (10), p.2209-2213
Hauptverfasser:	Lusseau, Jonathan, Uduagwu, Dickson, Robert, Frédéric, Landais, Yannick
Format:	Artikel
Sprache:	eng
Schlagworte:	amidination Catalysis Chemical Sciences Copper copper catalysis Decarboxylation Isocyanates N-alkylnitroisourea Organic chemistry peroxide Peroxides Polyurethane resins radical decarboxylation Synthesis urea
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Copper‐catalyzed decarboxylation of peroxides in the presence of O‐methyl‐N‐nitroisourea provides an access to O‐methyl‐N‐alkylnitroisoureas, an underdeveloped class of nitrogenated compounds, which can be regarded as isocyanate surrogates and find useful as AB‐type monomers, for polyurethane synthesis.
ISSN:	1615-4150 1615-4169
DOI:	10.1002/adsc.202400091