The very early-age behaviour of Ultra-High Performance Concrete containing ground granulated blast furnace slag

•30% of ordinary GGBS decreases the SP content, accelerates hydration reaction and decreases shrinkages.•50% of ordinary GGBS increases the SP content and delays the hydration reaction.•50% of superfine GGBS decreases SP content, accelerates hydration and has no significant effect on shrinkages. Ultra-High Performance Concrete (UHPC), despite being a relatively new kind of advanced cement-based material (featuring outstanding mechanical performance and excellent durability), has been deemed unsustainable due to its high cement content, thus increasing its carbon footprint. The large amounts of cement and silica fume (SF) can also raise both production costs and cracking risks due to the high early-age autogenous shrinkage. This paper addresses an innovative approach for developing a more sustainable UHPC involving an efficient application of ground granulated blast furnace slag (GGBS). Slags of two fineness levels are used, displaying a Blaine fineness of 420 m2/kg (SL1) and 700 m2/kg (SL2), respectively. These slags have been incorporated as volume replacements for 30% and 50% cement. The results analysis shows that it is indeed possible to produce SL2-based UHPC with a behavior similar to that of classical silica fume-based materials. The partial replacement of ordinary Portland cement (OPC) by 30% of GGBS (SL1 or SL2) improves workability, promotes the hydration reaction of cement and accelerates setting. In this case, the nucleation site effect of GGBS particles dominates; it seems to be directly correlated with the fineness of the slag used. Thus, the finer additions result in a significant acceleration of setting and hydration. The dilution effect is more sensitive at 50% of SL1 substitution. This prevailing effect delays the hydration reaction, prolongs setting times and decreases the peak of heat flow. In contrast however, this delay effect was not observed for the mixture containing 50% of SL2. Shrinkage measurements indicated that 30% of SL1 induces a slight reduction in early-age chemical and autogenous types of shrinkage. The most severe shrinkage is clearly found in mixtures incorporating 30% of SL2. This phenomenon may be due to the distribution of refined pores, which increases capillary tension. A more sustainable UHPC containing a high level of superfine slag (50%) with less autogenous shrinkage has been successfully produced.