8-Methyl-3-methylsulfanyl-8a,8b-dihydro-5 H -1-oxa-2,4-diazaacenaphthylene
In the tricyclic title compound, C 11 H 12 N 2 OS, the 2,3,4,5-tetrahydropyridine ring adopts a half-chair conformation. This ring makes dihedral angles of 27.72 (7) and 45.17 (7)°, respectively, with the isoxazole and the cyclohexa-1,3-diene rings while the isoxazole ring is oriented at an acute an...
Gespeichert in:
| Veröffentlicht in: | IUCrData 2021-06, Vol.6 (6), Article x210674 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 6 |
| container_start_page | |
| container_title | IUCrData |
| container_volume | 6 |
| creator | Abou, Akoun Bamba, Fanté Marrot, Jérôme Yaya, Soro Coustard, Jean-Marie |
| description | In the tricyclic title compound, C
11
H
12
N
2
OS, the 2,3,4,5-tetrahydropyridine ring adopts a half-chair conformation. This ring makes dihedral angles of 27.72 (7) and 45.17 (7)°, respectively, with the isoxazole and the cyclohexa-1,3-diene rings while the isoxazole ring is oriented at an acute angle of 63.46 (7)° with respect to the cyclohexa-1,3-diene ring. In the crystal, molecules associate
via
C—H...N hydrogen bonds and C—H...π interactions, forming a three-dimensional network. |
| doi_str_mv | 10.1107/S241431462100674X |
| format | Article |
| fullrecord | <record><control><sourceid>hal_cross</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_04417478v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>oai_HAL_hal_04417478v1</sourcerecordid><originalsourceid>FETCH-LOGICAL-c761-f7c4cc36a8b761c27a05a3d54c75f59586132f836e0d68f9ad6cb695d3ae33443</originalsourceid><addsrcrecordid>eNplkEtLw0AUhQdRsNT-AHfdCh2dm3lmWYoaJeLCLtwNN_MgkTQpiYrx15tYEcHVPffjnLM4hJwDuwRg-uopESA4CJUAY0qL5yMymxCd2PEffUoWff_CGAOjTZryGbk39CG8lkNNOd19i_6tjtiMwODKFNRX5eC7lspltqRA2w-kyUqMGD8RXWhwX06p0IQzchKx7sPi587J9uZ6u8lo_nh7t1nn1GkFNGonnOMKTTG-LtHIJHIvhdMyylQaBTyJhqvAvDIxRa9coVLpOQbOheBzcnGoLbG2-67aYTfYFiubrXM7MSYEaKHNO4xeOHhd1_Z9F-JvAJidprP_puNfBdJdvA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>8-Methyl-3-methylsulfanyl-8a,8b-dihydro-5 H -1-oxa-2,4-diazaacenaphthylene</title><source>DOAJ Directory of Open Access Journals</source><source>PubMed Central Open Access</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><creator>Abou, Akoun ; Bamba, Fanté ; Marrot, Jérôme ; Yaya, Soro ; Coustard, Jean-Marie</creator><creatorcontrib>Abou, Akoun ; Bamba, Fanté ; Marrot, Jérôme ; Yaya, Soro ; Coustard, Jean-Marie</creatorcontrib><description>In the tricyclic title compound, C
11
H
12
N
2
OS, the 2,3,4,5-tetrahydropyridine ring adopts a half-chair conformation. This ring makes dihedral angles of 27.72 (7) and 45.17 (7)°, respectively, with the isoxazole and the cyclohexa-1,3-diene rings while the isoxazole ring is oriented at an acute angle of 63.46 (7)° with respect to the cyclohexa-1,3-diene ring. In the crystal, molecules associate
via
C—H...N hydrogen bonds and C—H...π interactions, forming a three-dimensional network.</description><identifier>ISSN: 2414-3146</identifier><identifier>EISSN: 2414-3146</identifier><identifier>DOI: 10.1107/S241431462100674X</identifier><language>eng</language><publisher>International Union of Crystallography (IUCr) (Chester, England) [2016-....]</publisher><subject>Chemical Sciences</subject><ispartof>IUCrData, 2021-06, Vol.6 (6), Article x210674</ispartof><rights>Attribution</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c761-f7c4cc36a8b761c27a05a3d54c75f59586132f836e0d68f9ad6cb695d3ae33443</cites><orcidid>0000-0001-6902-1027 ; 0000-0002-5351-4908</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,864,885,27923,27924</link.rule.ids><backlink>$$Uhttps://hal.science/hal-04417478$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Abou, Akoun</creatorcontrib><creatorcontrib>Bamba, Fanté</creatorcontrib><creatorcontrib>Marrot, Jérôme</creatorcontrib><creatorcontrib>Yaya, Soro</creatorcontrib><creatorcontrib>Coustard, Jean-Marie</creatorcontrib><title>8-Methyl-3-methylsulfanyl-8a,8b-dihydro-5 H -1-oxa-2,4-diazaacenaphthylene</title><title>IUCrData</title><description>In the tricyclic title compound, C
11
H
12
N
2
OS, the 2,3,4,5-tetrahydropyridine ring adopts a half-chair conformation. This ring makes dihedral angles of 27.72 (7) and 45.17 (7)°, respectively, with the isoxazole and the cyclohexa-1,3-diene rings while the isoxazole ring is oriented at an acute angle of 63.46 (7)° with respect to the cyclohexa-1,3-diene ring. In the crystal, molecules associate
via
C—H...N hydrogen bonds and C—H...π interactions, forming a three-dimensional network.</description><subject>Chemical Sciences</subject><issn>2414-3146</issn><issn>2414-3146</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNplkEtLw0AUhQdRsNT-AHfdCh2dm3lmWYoaJeLCLtwNN_MgkTQpiYrx15tYEcHVPffjnLM4hJwDuwRg-uopESA4CJUAY0qL5yMymxCd2PEffUoWff_CGAOjTZryGbk39CG8lkNNOd19i_6tjtiMwODKFNRX5eC7lspltqRA2w-kyUqMGD8RXWhwX06p0IQzchKx7sPi587J9uZ6u8lo_nh7t1nn1GkFNGonnOMKTTG-LtHIJHIvhdMyylQaBTyJhqvAvDIxRa9coVLpOQbOheBzcnGoLbG2-67aYTfYFiubrXM7MSYEaKHNO4xeOHhd1_Z9F-JvAJidprP_puNfBdJdvA</recordid><startdate>20210630</startdate><enddate>20210630</enddate><creator>Abou, Akoun</creator><creator>Bamba, Fanté</creator><creator>Marrot, Jérôme</creator><creator>Yaya, Soro</creator><creator>Coustard, Jean-Marie</creator><general>International Union of Crystallography (IUCr) (Chester, England) [2016-....]</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0001-6902-1027</orcidid><orcidid>https://orcid.org/0000-0002-5351-4908</orcidid></search><sort><creationdate>20210630</creationdate><title>8-Methyl-3-methylsulfanyl-8a,8b-dihydro-5 H -1-oxa-2,4-diazaacenaphthylene</title><author>Abou, Akoun ; Bamba, Fanté ; Marrot, Jérôme ; Yaya, Soro ; Coustard, Jean-Marie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c761-f7c4cc36a8b761c27a05a3d54c75f59586132f836e0d68f9ad6cb695d3ae33443</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemical Sciences</topic><toplevel>online_resources</toplevel><creatorcontrib>Abou, Akoun</creatorcontrib><creatorcontrib>Bamba, Fanté</creatorcontrib><creatorcontrib>Marrot, Jérôme</creatorcontrib><creatorcontrib>Yaya, Soro</creatorcontrib><creatorcontrib>Coustard, Jean-Marie</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>IUCrData</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abou, Akoun</au><au>Bamba, Fanté</au><au>Marrot, Jérôme</au><au>Yaya, Soro</au><au>Coustard, Jean-Marie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>8-Methyl-3-methylsulfanyl-8a,8b-dihydro-5 H -1-oxa-2,4-diazaacenaphthylene</atitle><jtitle>IUCrData</jtitle><date>2021-06-30</date><risdate>2021</risdate><volume>6</volume><issue>6</issue><artnum>x210674</artnum><issn>2414-3146</issn><eissn>2414-3146</eissn><abstract>In the tricyclic title compound, C
11
H
12
N
2
OS, the 2,3,4,5-tetrahydropyridine ring adopts a half-chair conformation. This ring makes dihedral angles of 27.72 (7) and 45.17 (7)°, respectively, with the isoxazole and the cyclohexa-1,3-diene rings while the isoxazole ring is oriented at an acute angle of 63.46 (7)° with respect to the cyclohexa-1,3-diene ring. In the crystal, molecules associate
via
C—H...N hydrogen bonds and C—H...π interactions, forming a three-dimensional network.</abstract><pub>International Union of Crystallography (IUCr) (Chester, England) [2016-....]</pub><doi>10.1107/S241431462100674X</doi><orcidid>https://orcid.org/0000-0001-6902-1027</orcidid><orcidid>https://orcid.org/0000-0002-5351-4908</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2414-3146 |
| ispartof | IUCrData, 2021-06, Vol.6 (6), Article x210674 |
| issn | 2414-3146 2414-3146 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_04417478v1 |
| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Chemical Sciences |
| title | 8-Methyl-3-methylsulfanyl-8a,8b-dihydro-5 H -1-oxa-2,4-diazaacenaphthylene |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-12T16%3A03%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-hal_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=8-Methyl-3-methylsulfanyl-8a,8b-dihydro-5%20H%20-1-oxa-2,4-diazaacenaphthylene&rft.jtitle=IUCrData&rft.au=Abou,%20Akoun&rft.date=2021-06-30&rft.volume=6&rft.issue=6&rft.artnum=x210674&rft.issn=2414-3146&rft.eissn=2414-3146&rft_id=info:doi/10.1107/S241431462100674X&rft_dat=%3Chal_cross%3Eoai_HAL_hal_04417478v1%3C/hal_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |