8-Methyl-3-methylsulfanyl-8a,8b-dihydro-5 H -1-oxa-2,4-diazaacenaphthylene

In the tricyclic title compound, C 11 H 12 N 2 OS, the 2,3,4,5-tetrahydropyridine ring adopts a half-chair conformation. This ring makes dihedral angles of 27.72 (7) and 45.17 (7)°, respectively, with the isoxazole and the cyclohexa-1,3-diene rings while the isoxazole ring is oriented at an acute an...

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Veröffentlicht in:IUCrData 2021-06, Vol.6 (6), Article x210674
Hauptverfasser: Abou, Akoun, Bamba, Fanté, Marrot, Jérôme, Yaya, Soro, Coustard, Jean-Marie
Format: Artikel
Sprache:eng
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Zusammenfassung:In the tricyclic title compound, C 11 H 12 N 2 OS, the 2,3,4,5-tetrahydropyridine ring adopts a half-chair conformation. This ring makes dihedral angles of 27.72 (7) and 45.17 (7)°, respectively, with the isoxazole and the cyclohexa-1,3-diene rings while the isoxazole ring is oriented at an acute angle of 63.46 (7)° with respect to the cyclohexa-1,3-diene ring. In the crystal, molecules associate via C—H...N hydrogen bonds and C—H...π interactions, forming a three-dimensional network.
ISSN:2414-3146
2414-3146
DOI:10.1107/S241431462100674X