The error structure of impedance spectra for systems with a large ohmic resistance with respect to the polarization impedance

The error structure of impedance spectra for systems with a large ohmic resistance with respect to the polarization impedance

Electrochemical impedance spectra were obtained for polyaniline membranes in weak and strong acid electrolytes. The measurement model approach for error analysis was used to show that the standard deviation of the real and imaginary parts of the impedance were equal, even for systems containing a la...

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Veröffentlicht in:Journal of the Electrochemical Society 1996-12, Vol.143 (12), p.3880-3890
Hauptverfasser: ORAZEM, M. E, MOUSTAFID, T. E, DESLOUIS, C, TRIBOLLET, B
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Chemical Sciences
Chemistry
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General and physical chemistry
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container_end_page 3890
container_issue 12
container_start_page 3880
container_title Journal of the Electrochemical Society
container_volume 143
creator ORAZEM, M. E
MOUSTAFID, T. E
DESLOUIS, C
TRIBOLLET, B
description Electrochemical impedance spectra were obtained for polyaniline membranes in weak and strong acid electrolytes. The measurement model approach for error analysis was used to show that the standard deviation of the real and imaginary parts of the impedance were equal, even for systems containing a large solution resistance with respect to the polarization impedance. These results were confirmed using analogue RC circuits that did not require use of the measurement model approach. A model for the error structure is proposed that is in agreement with data obtained for large and small values of the solution resistance.
doi_str_mv 10.1149/1.1837311
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subjects Chemical Sciences
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
title The error structure of impedance spectra for systems with a large ohmic resistance with respect to the polarization impedance
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