Enantiopure natural deep eutectic solvents for metal-organic framework chiral induction

A green alternative approach to the chiral induction of a metal-organic framework (MOF) has been explored using the natural deep eutectic solvents (DES) proline : thymol (1 : 7) and menthol : thymol (1 : 1). These solvents have been successfully employed for the preparation of the MIL-103 MOF and le...

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Veröffentlicht in:	Green chemistry : an international journal and green chemistry resource : GC 2023-11, Vol.25 (22), p.913-918
Hauptverfasser:	Maia, Renata A, Fluck, Audrey, Maxim, Catalin, Louis, Benoît, Baudron, Stéphane A
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Circular dichroism Dichroism Green chemistry Material chemistry Menthol Metal-organic frameworks Porous materials Solvents Thymol
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Beschreibung
Zusammenfassung:	A green alternative approach to the chiral induction of a metal-organic framework (MOF) has been explored using the natural deep eutectic solvents (DES) proline : thymol (1 : 7) and menthol : thymol (1 : 1). These solvents have been successfully employed for the preparation of the MIL-103 MOF and lead to an enantioenrichment of the porous material when used in enantiopure form, as demonstrated by circular dichroism. The enantioenrichment of the MIL-103 metal-organic framework using the natural deep eutectic solvents (DES) proline : thymol (1 : 7) and menthol : thymol (1 : 1) in their enantiopure form has been demonstrated by circular dichroism.
ISSN:	1463-9262 1463-9270
DOI:	10.1039/d3gc02993j