Syntheses of S-Enantiomers of Hanishin, Longamide B, and Longamide B Methyl Ester from l-Aspartic Acid β-Methyl Ester: Establishment of Absolute Stereochemistry

Total syntheses of enantiopure hanishin, longamide B, and longamide B methyl ester are described. Absolute configurations of these natural products have been established.

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Veröffentlicht in:Journal of organic chemistry 2005-10, Vol.70 (22), p.9081-9084
Hauptverfasser: Patel, Jignesh, Pelloux-Léon, Nadia, Minassian, Frédéric, Vallée, Yannick
Format: Artikel
Sprache:eng
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Zusammenfassung:Total syntheses of enantiopure hanishin, longamide B, and longamide B methyl ester are described. Absolute configurations of these natural products have been established.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo051555l