Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structure

Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structure

Three examples of nitrido-functionalized polyoxometalate species are reported, namely (n-Bu4N)4[PW11O39(OsN)] (1), (n-Bu4N)4[PW11O39(ReN)] (2), and (n-Bu4N)3[PW11O39(ReN)] (3), which feature the incorporation of [OsVI identical to N]3+, [ReVI identical to N]3+ and [ReVII identical to N]4+ fragments,...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-12 (24), p.2970-2971
Hauptverfasser: Kwen, Haidoo, Tomlinson, Sean, Maatta, Eric A, Dablemont, Céline, Thouvenot, René, Proust, Anna, Gouzerh, Pierre
Format: Artikel
Sprache:eng
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Chemical Sciences
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Zusammenfassung:Three examples of nitrido-functionalized polyoxometalate species are reported, namely (n-Bu4N)4[PW11O39(OsN)] (1), (n-Bu4N)4[PW11O39(ReN)] (2), and (n-Bu4N)3[PW11O39(ReN)] (3), which feature the incorporation of [OsVI identical to N]3+, [ReVI identical to N]3+ and [ReVII identical to N]4+ fragments, respectively, into the framework of a Keggin-type heteropolyanion.
ISSN:1359-7345
1364-548X
DOI:10.1039/b209173a