Sequential chiral induction between organic and inorganic supramolecular helical assemblies for the in situ formation of chiral carbon dots

Self-organised helical bilayers of dicationic gemini surfactants confined in helical silica nanospace were transformed to carbon dots (CDots) pyrolysis. These water-dispersible CDots exhibit electronic absorption spanning the UV and visible range and possess symmetrical circular dichroism (CD) signa...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-08, Vol.59 (64), p.9762-9765
Hauptverfasser: Pranee, Piyanan, Scalabre, Antoine, Labrugere, Christine, Ryu, Naoya, Yano, Akira, Hano, Nanami, Talaga, David, Okazaki, Yutaka, Pouget, Emilie, Nlate, Sylvain, Bonhommeau, Sébastien, Takafuji, Makoto, Wada, Takehiko, Ihara, Hirotaka, Buffeteau, Thierry, Bassani, Dario M, Oda, Reiko
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Sprache:eng
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Zusammenfassung:Self-organised helical bilayers of dicationic gemini surfactants confined in helical silica nanospace were transformed to carbon dots (CDots) pyrolysis. These water-dispersible CDots exhibit electronic absorption spanning the UV and visible range and possess symmetrical circular dichroism (CD) signals, the sign of which depends on the handedness of the helices.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc02057f