Sustainable One-Pot Synthesis and Polycondensation of a Levoglucosenone-Derived Cyclic Acetal Diol

The already described one-pot two-step hydration/reduction of levoglucosenone (LGO) into (1R,2S,5R)-6,8-dioxabicyclo­[3.2.1]­octane-2,4-diol (HO-LGOL) was improved by replacing 50 mol % of Et3N by 5 mol % of K3PO4, a more sustainable base. The sterically hindered diol was then subjected to polyconde...

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Veröffentlicht in:ACS sustainable chemistry & engineering 2022-08, Vol.10 (31), p.10132-10143
Hauptverfasser: Diot-Néant, Florian, Mouterde, Louis M. M., Veith, Clémence, Couvreur, Julien, Miller, Stephen A., Allais, Florent
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Sprache:eng
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