Self and N2 collisional broadening of far-infrared methane lines at low-temperature with application to Titan

We report the measurement of broadening coefficients of pure rotational lines of methane at different pressure and temperature conditions. A total of 27 far-infrared spectra were recorded at the AILES beamline of the SOLEIL synchrotron at room-temperature, 200K and 120K, in a range of 10 to 800mbar. Self and N2 broadening coefficients and temperature dependence exponents of methane pure rotational lines have been measured in the 73–136cm−1 spectral range using multi-spectrum non-linear least squares fitting of Voigt profiles. These coefficients were used to model spectra of Titan that were compared to a selection of equatorial Cassini/CIRS spectra, showing a good agreement for a stratospheric methane mole fraction of (1.17 ± 0.08)%. •Far-infrared high-resolution spectroscopy of methane rotational lines.•Pressure broadening of pure rotational lines at low temperature.•Coefficients measured were used to model spectra of Titan that were compared to a selection of equatorial Cassini/CIRS spectra.