Click chemistry for the efficient preparation of functionalized [60]fullerene hexakis-adducts

Click chemistry for the efficient preparation of functionalized [60]fullerene hexakis-adducts

A Th-symmetrical C60 hexakis-adduct bearing 12 peripheral azide groups has been prepared and used to produce functionalized derivatives by the copper mediated Huisgen 1,3-dipolar cycloaddition of azides and alkynes.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2008 (21), p.2450-2452
Hauptverfasser: Iehl, Julien, Pereira de Freitas, Rossimiriam, Delavaux-Nicot, Béatrice, Nierengarten, Jean-François
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes - chemistry
Azides - chemistry
Chemical Sciences
Coordination chemistry
Copper - chemistry
Cyclization
Fullerenes - chemistry
Magnetic Resonance Spectroscopy - methods
Magnetic Resonance Spectroscopy - standards
Molecular Structure
Oxidation-Reduction
Reference Standards
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Beschreibung
Zusammenfassung:A Th-symmetrical C60 hexakis-adduct bearing 12 peripheral azide groups has been prepared and used to produce functionalized derivatives by the copper mediated Huisgen 1,3-dipolar cycloaddition of azides and alkynes.
ISSN:1359-7345
1364-548X
DOI:10.1039/b804393k