Distribution pattern of mercury in northern Barents Sea and Eurasian Basin surface sediment

Marine sediment is a significant sink for the global pollutant mercury. In a rapidly changing Arctic region, mercury (Hg) bioaccumulation in the marine ecosystem remains a prominent environmental issue. Here, we report surface sediment (0–2 cm) concentrations of Hg and other toxic elements of intere...

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Veröffentlicht in:Marine pollution bulletin 2022-12, Vol.185, p.114272, Article 114272
Hauptverfasser: Kohler, Stephen G., Kull, Laura M., Heimbürger-Boavida, Lars-Eric, Ricardo de Freitas, Thaise, Sanchez, Nicolas, Ndungu, Kuria, Ardelan, Murat V.
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Sprache:eng
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Zusammenfassung:Marine sediment is a significant sink for the global pollutant mercury. In a rapidly changing Arctic region, mercury (Hg) bioaccumulation in the marine ecosystem remains a prominent environmental issue. Here, we report surface sediment (0–2 cm) concentrations of Hg and other toxic elements of interest (Cr, Ni, Zn, Cu, As, Cd, Pb) in the northern Barents Sea and Eurasian Basin. We observed average Hg concentrations of 65 ± 23 ng/g with the highest concentration of 116 ng/g in the Eurasian Basin. Our calculated enrichment factors suggest low anthropogenic enrichment for mercury, chromium, nickel, and copper. Mercury and trace element geographic patterns are best explained by the origin and transportation of fine grain sediment towards the Eurasian Basin, with scavenging by both particulate organic carbon and metal oxides as significant delivery mechanisms. •Mercury concentration in surface sediment ranged from 21 to 116 ng/g•Higher concentrations of Co, Cu, Hg, Pb in Eurasian Basin•Metal distributions most likely reflect scavenging processes and redox conditions.•Normalized Hg positively correlated to Mn, Co, Cu, Pb
ISSN:0025-326X
1879-3363
DOI:10.1016/j.marpolbul.2022.114272