Synthesis and Rearrangement of Intramolecularly Stabilized 1.sigma.2,3.sigma.2-Diphosphaallylic Cations into Intramolecularly Stabilized 1.sigma.1,3.sigma.3-Diphosphaallylic Cations

Synthesis and Rearrangement of Intramolecularly Stabilized 1.sigma.2,3.sigma.2-Diphosphaallylic Cations into Intramolecularly Stabilized 1.sigma.1,3.sigma.3-Diphosphaallylic Cations

Two equivalents of boron trifluoride-diethyl ether complex or 1 equiv of trifluoromethanesulfonic acid reacts with C-[bis(diisopropylamino)phosphino]-C,P-bis(diisopropylamino)phosphaalkene 1, cleaving one of the diisopropylamino substituents at the

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Veröffentlicht in:Journal of the American Chemical Society 1994-07, Vol.116 (14), p.6149-6152
Hauptverfasser: Soleilhavoup, Michele, Canac, Yves, Polozov, Alexander M, Baceiredo, Antoine, Bertrand, Guy
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Coordination chemistry
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Zusammenfassung:Two equivalents of boron trifluoride-diethyl ether complex or 1 equiv of trifluoromethanesulfonic acid reacts with C-[bis(diisopropylamino)phosphino]-C,P-bis(diisopropylamino)phosphaalkene 1, cleaving one of the diisopropylamino substituents at the
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00093a012