Synthesis, Reactivity, and Ligand Properties of a Stable Alkyl Carbene

Synthesis, Reactivity, and Ligand Properties of a Stable Alkyl Carbene

Stable tert-butyl diisopropylamino carbene is more nucleophilic but also more electrophilic than diamino carbenes; it undergoes cyclopropanation reactions and easily binds to metal fragments.

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Veröffentlicht in:Journal of the American Chemical Society 2004-07, Vol.126 (28), p.8670-8671
Hauptverfasser: Lavallo, Vincent, Mafhouz, John, Canac, Yves, Donnadieu, Bruno, Schoeller, Wolfgand W, Bertrand, Guy
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Chemistry
Coordination chemistry
Exact sciences and technology
Free radicals chemistry
Organic chemistry
Reactivity and mechanisms
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Beschreibung
Zusammenfassung:Stable tert-butyl diisopropylamino carbene is more nucleophilic but also more electrophilic than diamino carbenes; it undergoes cyclopropanation reactions and easily binds to metal fragments.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja047503f