Effects of various surface treatments on Aloe Vera fibers used as reinforcement in poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) biocomposites
The aim of this study was to assess the effect of various surface treatments on Aloe Vera fibers (AVF) used as reinforcement in PHBHHx biocomposites prepared by melt compounding. AVF were subjected to various surface treatments including alkaline, organo-silanes and combined alkaline/organo-silanes...
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Veröffentlicht in: | Polymer degradation and stability 2020-05, Vol.175, p.109131, Article 109131 |
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Zusammenfassung: | The aim of this study was to assess the effect of various surface treatments on Aloe Vera fibers (AVF) used as reinforcement in PHBHHx biocomposites prepared by melt compounding. AVF were subjected to various surface treatments including alkaline, organo-silanes and combined alkaline/organo-silanes treatments. Both untreated and treated AVF were added to PHBHHx at filler content of 20 wt% and the resulted biocomposites were characterized using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), water absorption test and rheological measurements. The study showed that the combined alkaline/organo-silanes treatment of AVF resulted in better morphology and properties of PHBHHx biocomposite compared to untreated AVF and those treated either with alkaline or with organosilanes. Indeed, SEM analysis of the fracture surface of PHBHHx/AVF treated with combined alkaline-organosilanes showed better fiber-matrix interactions compared to the other samples. As a result, rheological properties, i.e., complex viscosity (η∗), storage modulus (G′) and loss modulus (G″) were increased. Higher resistance to water absorption was observed for PHBHHx/AVF treated with combined alkaline-organosilanes. Whereas, the various surface fiber treatments led to no noticeable change in thermal characteristics of the biocomposites. This study highlights the effectiveness of combined alkaline/organo-silanes treatment of AVF over alkaline and organo-silanes and their applications in PHBHHx biocomposites as an interesting source of cellulosic reinforcing materials.
•Effect of surface treatments on Aloe Vera fibers (AVF) used as reinforcement in PHBHHx biocomposites.•Morphological and properties characterization of AVF and PHBHHx/AVF: 80/20 (w/w) biocomposite before and after treatments.•Improvement in fiber-matrix interface achieved by the combined alkaline-organosilanes treatment of AVF.•Interesting AVF source of cellulosic reinforcement materials. |
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ISSN: | 0141-3910 1873-2321 |
DOI: | 10.1016/j.polymdegradstab.2020.109131 |